A switchable dual organocatalytic system and the enantioselective total synthesis of the quadrane sesquiterpene suberosanone
The combination of aminocatalysis with N-heterocyclic carbene catalysis has been extended to a switchable dual catalytic system, which allowed a direct enantioselective entry to bridged bicyclo[3.n.1] ring systems and the total synthesis of the natural product (1R)-suberosanone.
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Published in: | Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (39), p.6565-6568 |
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Main Authors: | , , , , , , , |
Format: | Article |
Language: | eng |
Subjects: | |
Online Access: | Request full text |
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Summary: | The combination of aminocatalysis with N-heterocyclic carbene catalysis has been extended to a switchable dual catalytic system, which allowed a direct enantioselective entry to bridged bicyclo[3.n.1] ring systems and the total synthesis of the natural product (1R)-suberosanone. |
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ISSN: | 1359-7345 1364-548X |