Rhenium calix[4]arenes: precursors to novel imaging and cancer therapy agents

Interaction of [ReOCl3(PPh3)2] with tert-butylcalix[4]areneH4, Cax(OH)4, in the presence of MOtBu (M = Na, K), or MH, under anaerobic conditions affords the isostructural rhenium(V) oxo complexes [Re(O)(PPh3)Cax(O)4M(NCMe)2] · 4MeCN [M = Na, (1); K, (2)] containing an alkali-metal cation within an e...

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Bibliographic Details
Main Authors: Carl Redshaw, Xiaoming Liu, Shuzong Zhan, David L. Hughes, Hugo Baillie-Johnson, Mark Elsegood, Sophie H. Dale
Format: Default Article
Published: 2008
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Online Access:https://hdl.handle.net/2134/15564
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