Iron(III) bromide catalyzed bromination of 2-tert-butylpyrene and corresponding position-dependent aryl-functionalized pyrene derivatives

Iron(III) bromide catalyzed bromination of 2-tert-butylpyrene and corresponding position-dependent aryl-functionalized pyrene derivatives

The present work probes the bromination mechanism of 2-tert-butylpyrene (1), which regioselectively affords mono-, di-, tri- and tetra-bromopyrenes, by theoretical calculation and detailed experimental methods. The bromine atom may be directed to the K-region (positions 5- and 9-) instead of the mor...

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Bibliographic Details
Main Authors: Xing Feng, Jian-Yong Hu, Hirotsugu Tomiyasu, Zhu Tao, Carl Redshaw, Mark Elsegood, Lynne Horsburgh, Simon J. Teat, Xian-Fu Wei, Takehiko Yamato
Format: Default Article
Published: 2015
Subjects:
Other chemical sciences not elsewhere classified
Polycyclic aromatic-hydrocarbons
Photophysical properties
Blue emmitters
Efficient
PI
Borylation
Substitution
Dendrimers
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/18635
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https://hdl.handle.net/2134/18635

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