Early transition metal complexes bearing a C-capped tris(phenolate) ligand incorporating a pendant imine arm: synthesis, structure, and ethylene polymerization behavior
The ligand 3-[2,2′-methylenebis(4,6-di-tert-butylphenol)-5-tert-butylsalicylidene-(2,6-diisopropyl)phenylimine] (L1H3) was reacted with MCl4 (M = Ti, Zr) or MCl5 (M = Nb, Ta) to give complexes of the type [MCl2(L1H2)2] (M = Ti (1); Zr (2)), [NbCl3(L1H)] (3), or [TaCl4(L1H2)] (4), respectively. Singl...
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| Main Authors: | , , , , |
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| Format: | Default Article |
| Published: |
2008
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| Subjects: | |
| Online Access: | https://hdl.handle.net/2134/15782 |
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