Synthesis and conformational studies of calixarene analogue chiral [3.3.1]metacyclophanes

Synthesis and conformational studies of calixarene analogue chiral [3.3.1]metacyclophanes

Trihydroxy[3.3.1]metacyclophane, which can be regarded as an unsymmetrical or incomplete "homocalix[3]arene", has been prepared from rimethoxy[3.3.1]metacyclophane by demethylation with trimethylsilyl iodide in MeCN. Di-O-methylation at the lower rim of trihydroxy[3.3.1]metacyclophane in t...

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Bibliographic Details
Main Authors: Md. Monarul Islam, Tomiyasu Hirotsugu, Pierre Thuery, Taisuke Matsumoto, Junji Tanaka, Mark Elsegood, Carl Redshaw, Takehiko Yamato
Format: Default Article
Published: 2015
Subjects:
Other chemical sciences not elsewhere classified
Metacyclophanes
Macrocycles
Calixarenes
Intramolecular hydrogen bonding
Oemethylation
Chirality
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/18636
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https://hdl.handle.net/2134/18636

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