Reversible P–P bond cleavage at an iridium(iii) metal centre
Treatment of a κ1-P-monodentate bicyclic diphosphane iridium(III) complex with a labile gold(I) precursor afforded an unusual IrIII/AuI complex in which the P–P single bond has been cleaved. This reaction was cleanly reversed upon addition of tertiary phosphine. Carbon–carbon bond activation, across...
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| Main Authors: | , , , , , , , |
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| Format: | Default Article |
| Published: |
2022
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| Subjects: | |
| Online Access: | https://hdl.handle.net/2134/19668810.v1 |
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