Synthesis and characterisation of transition metal complexes of a novel 1,5‐benzodiazepine‐functionalised tertiary phosphine

Synthesis and characterisation of transition metal complexes of a novel 1,5‐benzodiazepine‐functionalised tertiary phosphine

The one-step synthesis (44% isolated yield) of the 1,5- benzodiazapine functionalised phosphine 1, C31H31N2OP, is reported. Bridge cleavage of {MCl(μ-Cl)(η5 -Cp*)}2 (M=Ir, Rh) with 2 equiv. of 1 in CH2Cl2 gave the mononuclear compounds [MCl2(η5 -Cp*)(P-1)] (M=Ir, 2a; M=Rh, 2b) in which 1 functions a...

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Bibliographic Details
Main Authors: Sean E. Durran, Mark Elsegood, Thomas A. Noble, Martin Smith, Thomas Gelbrich, Michael B Hursthouse, Mark E Light
Format: Default Article
Published: 2021
Subjects:
Inorganic chemistry not elsewhere classified
Inorganic & Nuclear Chemistry
Other Chemical Sciences
1,5-Benzodiazapines
C−H activation
Late-transition metals
Phosphine ligands
Structure elucidation
Inorganic Chemistry
Online Access:https://hdl.handle.net/2134/14626158.v1
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https://hdl.handle.net/2134/14626158.v1

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