Tailoring the Alkalinity of SnO2 Colloidal Suspension for High‐Performance and Stable Perovskite Solar Cells

The commercial tin oxide (SnO2) colloidal suspension is widely utilized as an electron transport layer (ETL) in high‐performance perovskite solar cells (PSCs). However, despite significant efforts have been proposed to address bulk transport and interface recombination issues, the PSC efficiency is...

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Bibliographic Details
Published in:Solar RRL 2024-06, Vol.8 (12), p.n/a
Main Authors: Shao, Zhiliang, Wang, Ming, Li, Xikang, Zou, Hechao, Ye, Fanghao, Liu, Siyang, Zhou, Hang, Xu, Ping, Li, Guijun
Format: Article
Language:English
Subjects:
perovskite solar cells
pH value
reassembly
SnO2
weak acid
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Summary:The commercial tin oxide (SnO2) colloidal suspension is widely utilized as an electron transport layer (ETL) in high‐performance perovskite solar cells (PSCs). However, despite significant efforts have been proposed to address bulk transport and interface recombination issues, the PSC efficiency is still limited to around 25%. In this study, the crucial role of the physicochemical characteristics of the SnO2 colloidal suspension in shaping the morphology, electrical properties, and optical properties of the SnO2 ETL is investigated. By controlling the pH value of the SnO2 solution with weak acids such as carbonic acid, the reassembly of metal oxide nanoparticles into smaller sizes with more homogeneous dispersion and dense interconnections is successfully induced. Consequently, the resulting SnO2 ETL exhibits enhanced crystallinity, high conductivity, low surface defects, and high optical transmittance. As a result, the efficiency of the target PSC is increased from 23.10% (control device) to 24.70%. This improvement is attributed to higher voltage, photocurrent, and fill factor compared to the relevant control samples. A similar device improvement using phosphoric acid is observed, indicating that the approach represents a universal technique to further enhance the quality of SnO2 ETL for large‐area, high‐efficiency, and stable PSCs. This study investigates the crucial role of the physicochemical characteristics of the SnO2 colloidal suspension in shaping the morphology, electrical properties, and optical properties of the SnO2 electron transport layer (ETL). The acid‐modified SnO2 ETL exhibits advanced properties, resulting in perovskite solar cells (PSCs) with 24.70% power conversion efficiency (PCE) and good stability.
ISSN:2367-198X
2367-198X
DOI:10.1002/solr.202400292