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Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AMI calculations
Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2] with PPh3 yielded the oxomolybdenum(IV) species [MoOCl 2 (THF)2 ] (1) by the removal of one oxygen atom as PPh3 O. The complexes [MoOCl 2(=NC6H4CN)] 2, [MoOCl2 (CNC6H4 OH)] 3, [MoOCl2(=NC6H4NH2)] 4, and [MoOCl2(=NC6H4...
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Published in: | Turkish journal of chemistry 2009, Vol.33 (5), p.693-708 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Online Access: | Get full text |
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Summary: | Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO2 Cl2 (THF)2] with PPh3
yielded the oxomolybdenum(IV) species [MoOCl 2 (THF)2 ] (1) by the removal of one oxygen atom as PPh3 O.
The complexes [MoOCl 2(=NC6H4CN)] 2, [MoOCl2 (CNC6H4 OH)] 3, [MoOCl2(=NC6H4NH2)] 4, and
[MoOCl2(=NC6H4OCH3)] 5, were synthesized by the reactions of [MoOCl 2 (THF)2] with XC6H4Y (X
= NH2 , Y = CN; X= CN, Y = OH; X = Y = NH2; X = NH2, Y = OCH3) . All the new compounds
were characterized by elemental analyses, and FTIR, UV-Vis, and 1 H- and 13 C-NMR spectra. Geometrical
parameters and molecular orbital calculations showed that compounds 2-5 are stabilized by a charge transfer
between the Mo center and the phenyl ring. |
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ISSN: | 1300-0527 1303-6130 |