Efficient Reductions of Nitroarenes with SnCl2 in Ionic Liquid

Abstract Mild, eco-friendly and fast reductions of nitroarenes to aminoarenes have been accomplished using stannous chloride dihydrate in ionic liquid tetrabutylammonium bromide (TBAB) that provides unsolvated nucleophilic bromide ion. Improved yields, lower reaction time, generality, and a less dem...

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Bibliographic Details
Published in:Synlett 2004-08, Vol.2004 (10), p.1835-1837
Main Author: De, Prithwiraj
Format: Article
Language:English
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Summary:Abstract Mild, eco-friendly and fast reductions of nitroarenes to aminoarenes have been accomplished using stannous chloride dihydrate in ionic liquid tetrabutylammonium bromide (TBAB) that provides unsolvated nucleophilic bromide ion. Improved yields, lower reaction time, generality, and a less demanding work-up procedure are the notable features of this protocol.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2004-830847