Surface and bulk electronic structures of heavily Mg-doped InN epilayer by hard X-ray photoelectron spectroscopy

To evaluate the polarity, energy band diagram, and oxygen (O) distribution of a heavily Mg-doped InN (InN:Mg+) epilayer with a Mg concentration of 1.0 ± 0.5 × 1020 cm−3, the core-level and valence band (VB) photoelectron spectra are investigated by angle-resolved soft and hard X-ray photoelectron sp...

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Published in:Journal of applied physics 2017-03, Vol.121 (9)
Main Authors: Imura, Masataka, Tsuda, Shunsuke, Nagata, Takahiro, Banal, Ryan G., Yoshikawa, Hideki, Yang, AnLi, Yamashita, Yoshiyuki, Kobayashi, Keisuke, Koide, Yasuo, Yamaguchi, Tomohiro, Kaneko, Masamitsu, Uematsu, Nao, Wang, Ke, Araki, Tsutomu, Nanishi, Yasushi
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Language:eng
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Summary:To evaluate the polarity, energy band diagram, and oxygen (O) distribution of a heavily Mg-doped InN (InN:Mg+) epilayer with a Mg concentration of 1.0 ± 0.5 × 1020 cm−3, the core-level and valence band (VB) photoelectron spectra are investigated by angle-resolved soft and hard X-ray photoelectron spectroscopies. The InN:Mg+ epilayers are grown by radio-frequency plasma-assisted molecular beam epitaxy. In this doping level, the polarity inversion from In-polar to N-polar occurs with the increase in the Mg flow rate under the same growth conditions, and the VB spectrum clearly indicates the direction of polarity of InN:Mg+, which is N-polar. The energy band diagram is considered to exhibit a two-step downward bending structure due to the coexistence of the n+ surface electron accumulation layer and heavily Mg-doped p+ layer formed in the bulk. The O concentration rapidly increases until ∼4 nm with respect to the surface, which is deduced to be one of the reasons of the formation of the anomalous two-step energy band profile.
ISSN:0021-8979
1089-7550