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Multilevel sensitization of Er 3 + in low-temperature-annealedsilicon-rich SiO 2

The dynamics of Er 3 + excitation in low-temperature-annealed Si-rich SiO 2 are studied. It is demonstrated that Si-excess-related indirect excitation is fast (transfer time τ tr < 27   ns ) and occurs into higher lying Er 3 + levels as well as directly into the first excited state ( I 4 13 / 2 )...

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Bibliographic Details
Published in:Applied physics letters 2008-12, Vol.93 (23), p.233120-233120-3
Main Authors: Savchyn, Oleksandr, Todi, Ravi M., Coffey, Kevin R., Kik, Pieter G.
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Summary:The dynamics of Er 3 + excitation in low-temperature-annealed Si-rich SiO 2 are studied. It is demonstrated that Si-excess-related indirect excitation is fast (transfer time τ tr < 27   ns ) and occurs into higher lying Er 3 + levels as well as directly into the first excited state ( I 4 13 / 2 ) . By monitoring the time-dependent Er 3 + emission at 1535 nm, the multilevel nature of the Er 3 + sensitization is shown to result in two types of excitation of the I 4 13 / 2 state: a fast excitation process ( τ tr < 27   ns ) directly into the I 4 13 / 2 level and a slow excitation process due to fast excitation into Er 3 + levels above the I 4 13 / 2 level, followed by internal Er 3 + relaxation with a time constant τ 32 > 2.3   μ s . The fast and slow excitations of the I 4 13 / 2 level account for an approximately equal fraction of the excitation events: 45%-50% and 50%-55%, respectively.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.3044480