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Facile preparation of high-performance Mn and Mg co-doped FeO nanorod for lithium-ion battery anode from refined green alum slag-a "turn waste into treasure" strategy

In this work, a "turn waste into treasure" strategy is proposed to synthesize Fe 2 O 3 and use it as a lithium-ion battery (LIB) anode from green alum slag, a by-product of TiO 2 production in the industry. Through this method, a heteroatom-doped Fe 2 O 3 was obtained and showed a stable s...

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Bibliographic Details
Published in:New journal of chemistry 2024-04, Vol.48 (17), p.766-7668
Main Authors: Yang, Gang, Zhu, Piao, Liu, Jinru, Liu, Jiang, Liao, Hailong, Wu, Xiulin, Sun, Xiujuan, Liu, Enhui, Ding, Rui, Gao, Ping
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Summary:In this work, a "turn waste into treasure" strategy is proposed to synthesize Fe 2 O 3 and use it as a lithium-ion battery (LIB) anode from green alum slag, a by-product of TiO 2 production in the industry. Through this method, a heteroatom-doped Fe 2 O 3 was obtained and showed a stable specific capacity of 1209 mA h g −1 at 500 mA g −1 , which was superior to pure-Fe 2 O 3 that was prepared in the laboratory. Besides, the full battery was assembled with Fe 2 O 3 as the anode, and the specific capacity was maintained at 102 mA h g −1 after 100 cycles of stable cycling at 1.0 A g −1 , showing excellent cycling and rate performance. This work offers a green low-cost and promising option for the development of LIBs anode materials and making TiO 2 industrial production more economical and environmentally friendly. Herein, value-added Fe 2 O 3 was recovered from green alum slag, a by-product of TiO 2 production in the industry. It worked well in LIBs as anode, showed a stable specific capacity of 1209 mA h g −1 at 500 mA g −1 .
ISSN:1144-0546
1369-9261
DOI:10.1039/d4nj00429a