Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CFSONa

This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac) 3 . The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance. Mn(acac) 3 catalyzed photoinduce...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2020-08, Vol.18 (33), p.6483-6486
Main Authors: Long, Wenhao, Lian, Pengcheng, Li, Jingjing, Wan, Xiaobing
Format: Article
Language:English
Online Access:Get full text
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Summary:This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac) 3 . The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance. Mn(acac) 3 catalyzed photoinduced hydroxytrifluoromethylation of aliphatic alkenes with CF 3 SO 2 Na was well established.
ISSN:1477-0520
1477-0539
DOI:10.1039/d0ob01322f