Iron ruthenium: syntheses, structures and IR spectroelectrochemical characterisation of half-sandwich Group 8 acetylide complexes

A convenient modification to the established synthetic routes for the preparation of complexes [M(C&z.tbd;CR)(dppe)Cp′] (M = Fe, Ru; Cp′ = η 5 -C 5 H 5 (Cp), η 5 -C 5 Me 5 (Cp*); R = C 6 H 5 , C 6 H 4 - p -OMe, C 6 H 4 - p -NO 2 , t Bu) and [Ru(C&z.tbd;CR)(PPh 3 ) 2 Cp] from the correspondin...

Full description

Saved in:
Bibliographic Details
Published in:New journal of chemistry 2021-08, Vol.45 (33), p.14932-14943
Main Authors: Harrison, Daniel P, Kumar, Varshini J, Noppers, Johanna N, Gluyas, Josef B. G, Sobolev, Alexandre N, Moggach, Stephen A, Low, Paul J
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A convenient modification to the established synthetic routes for the preparation of complexes [M(C&z.tbd;CR)(dppe)Cp′] (M = Fe, Ru; Cp′ = η 5 -C 5 H 5 (Cp), η 5 -C 5 Me 5 (Cp*); R = C 6 H 5 , C 6 H 4 - p -OMe, C 6 H 4 - p -NO 2 , t Bu) and [Ru(C&z.tbd;CR)(PPh 3 ) 2 Cp] from the corresponding [MCl(PP)Cp′] complex and the alkyne HC&z.tbd;CR via an intermediate vinylidene is described. The complexes are generally obtained as high quality crystalline samples directly from the reaction mixture. In agreement with previous studies, the iron complexes undergo a predominantly metal-centred oxidation, whilst there is greater involvement of the acetylide ligand in the oxidation processes associated with the ruthenium analogues. Analysis of the redox properties and spectroelectrochemical investigations reveal limited differences in the gross electronic structures of the Cp vs. Cp* derivatives in each of the Fe and Ru series. A synthetic 'trick' affording complexes [M(C&z.tbd;CR)(dppe)Cp′] (M = Fe, Ru) in high purity directly from the reaction vessel is described.
ISSN:1144-0546
1369-9261
DOI:10.1039/d0nj03093g