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Accelerated physical ageing of poly(1,4-cyclohexylenedimethylene-co-2,2,4,4-tetramethyl-1,3-cyclobutanediol terephthalate)Electronic supplementary information (ESI) available. See DOI: 10.1039/c9ra00925f
Successfully evaluating plastic lifetime requires understanding of the relationships between polymer dynamics and mechanical performance as a function of thermal ageing. The relatively high T g ( T g = 110 °C) of poly(1,4-cyclohexylenedimethylene- co -2,2,4,4-tetramethyl-1,3-cyclobutanediol terephth...
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Main Authors: | , , , |
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Format: | Article |
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Online Access: | Get full text |
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Summary: | Successfully evaluating plastic lifetime requires understanding of the relationships between polymer dynamics and mechanical performance as a function of thermal ageing. The relatively high
T
g
(
T
g
= 110 °C) of poly(1,4-cyclohexylenedimethylene-
co
-2,2,4,4-tetramethyl-1,3-cyclobutanediol terephthalate) (PCTT) renders it useful as a substituent for PET in higher temperature applications. This work links thermal ageing and mechanical performance of a commercial PCTT plastic after exposure to 40-80 °C for up to 2950 h. No chemical or conformational changes were found while pronounced physical ageing, measured as enthalpic relaxation, caused yield hardening (28% increase in yield strength) and embrittlement (80% decrease in toughness). Enthalpic relaxation increased with temperature and time to 3.8 J g
−1
and correlated to the determined toughness and yield strength. Finally, a 9% increase in Young's modulus was observed independent of temperature and with no correlation to enthalpic relaxation. Enthalpic relaxation followed Vogel-Fulcher-Tammann behaviour, while yield strength and charpy v-notch toughness followed Arrhenius behaviour enabling prediction of the different properties with time and temperature.
Poly(1,4-cyclohexylenedimethylene-
co
-2,2,4,4-tetramethyl-1,3-cyclobutanediol terephthalate) shows physical ageing, without chemical degradation, resulting in 80% impact toughness decrease. |
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ISSN: | 2046-2069 |
DOI: | 10.1039/c9ra00925f |