Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiatorsElectronic supplementary information (ESI) available: Devices, methods and procedures, analytical supporting material: NMR spectra, GPC traces and MALDI-TOF chromatograms. See DOI: 10.1039/c8sc04729d

A hydrogenated frustrated Lewis pair ([TMPH + ][HB(C 6 F 5 ) 3 − ]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequen...

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Main Authors: Sáez, Rubén, McArdle, Ciaran, Salhi, Fouad, Marquet, Jordi, Sebastián, Rosa M
Format: Article
Language:English
Online Access:Get full text
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Summary:A hydrogenated frustrated Lewis pair ([TMPH + ][HB(C 6 F 5 ) 3 − ]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials. Controlled living anionic polymerization of cyanoacrylates promoted by a hydrogenated frustrated Lewis pair ([TMPH + ][HB(C 6 F 5 ) 3 − ]). Preparation of designed block copolymers.
ISSN:2041-6520
2041-6539
DOI:10.1039/c8sc04729d