Luminescent lanthanide (Eu()) cross-linked supramolecular metallo co-polymeric hydrogels: the effect of ligand symmetry

Two lanthanide luminescent naphthyl-dipicolinic amide ( dpa ) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of...

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Bibliographic Details
Published in:	Chemical communications (Cambridge, England) England), 2019-02, Vol.55 (12), p.1754-1757
Main Authors:	Bradberry, Samuel J, Dee, Garret, Kotova, Oxana, McCoy, Colin P, Gunnlaugsson, Thorfinnur
Format:	Article
Language:	eng
Subjects:	Chemical synthesis Crosslinking Graft copolymers Hydrogels Ligands Metallography Polymer gels Symmetry
Online Access:	Request full text
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Summary:	Two lanthanide luminescent naphthyl-dipicolinic amide ( dpa ) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented; the results demonstrate the importance of the ligand symmetry for the Eu( iii ) emission from the hydrogels. Two lanthanide luminescent naphthyl-dipicolinic amide ( dpa ) methacrylate monomers for the synthesis of grafted supramolecular co-polymer gels (hydrogels), and their use as additional crosslinks in robust covalently cross-linked HEMA hydrogels is presented.
ISSN:	1359-7345 1364-548X