Sub-micron spheres of an imine-based covalent organic framework: supramolecular functionalization and water-dispersibilityElectronic supplementary information (ESI) available: Additional experimental data. See DOI: 10.1039/c6ce02200f

The one-pot room-temperature condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-benzenetricarboxaldehyde in acetone leads to the fast formation of a homogeneous dispersion of well-defined spherical particles of an imine-based covalent organic framework ( sRT-COF-1 ). Supramolec...

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Main Authors: Rodríguez-San-Miguel, David, Corral-Pérez, Juan J, Gil-González, Eva, Cuellas, David, Arauzo, Jesús, Monsalvo, Victor M, Carcelén, Verónica, Zamora, Félix
Format: Article
Language:English
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Summary:The one-pot room-temperature condensation reaction between 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-benzenetricarboxaldehyde in acetone leads to the fast formation of a homogeneous dispersion of well-defined spherical particles of an imine-based covalent organic framework ( sRT-COF-1 ). Supramolecular functionalization of sRT-COF-1 with a variety of surfactants significantly increases the water dispersibility of sRT-COF-1 . Sub-micron spheres of an imine-based COF are formed in a fast and simple reaction and functionalized to increase its water dispersibility framework ( sRT-COF-1 ).
ISSN:1466-8033
DOI:10.1039/c6ce02200f