Solvothermal synthesis and characterization of two inorganic-organic hybrid materials based on bariumElectronic supplementary information (ESI) available: Figures (PXRD, NMR). CCDC SLUG-13, 772004; SLUG-14 772005. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt31518a

Two metal-organic frameworks containing barium were synthesized hydrothermally and investigated for their catalytic properties. Ba 2 F 2 [O 3 SC 2 H 4 SO 3 ] has barium fluoride layers linked by organic 1,2-ethanedisulfonate molecules. Ba[O 3 SC 2 H 4 SO 3 ] has discrete barium centers arranged in l...

Full description

Saved in:
Bibliographic Details
Main Authors: Abdollahian, Yashar, Hauser, Jesse L, Rogow, David L, Oliver, Allen G, Oliver, Scott R. J
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Two metal-organic frameworks containing barium were synthesized hydrothermally and investigated for their catalytic properties. Ba 2 F 2 [O 3 SC 2 H 4 SO 3 ] has barium fluoride layers linked by organic 1,2-ethanedisulfonate molecules. Ba[O 3 SC 2 H 4 SO 3 ] has discrete barium centers arranged in layers and connected covalently by ethanedisulfonate bridges. Thermogravimetric analysis showed that Ba 2 F 2 [O 3 SC 2 H 4 SO 3 ] is stable to ca. 325 °C and Ba[O 3 SC 2 H 4 SO 3 ] to ca. 375 °C. These materials expand the metal-organic frameworks available for group II metals bound to organodisulfonate linkers and are potentially useful for a range of heterogeneous acid catalysis reactions. Two new materials based on barium have been synthesized and characterized. These materials expand the metal-organic frameworks available for group II metals bound to organodisulfonate linkers and are potentially useful for a range of heterogeneous acid catalysis reactions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt31518a