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From starphenes to non-benzenoid linear conjugated polymers by substrate templating
Combining on-surface synthetic methods with the power of scanning tunneling microscopy to characterize novel materials at the single molecule level, we show how to steer the reactivity of one anthracene-based precursor towards different product nanostructures. Whereas using a Au(111) surface with th...
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Published in: | Nanoscale advances 2021-04, Vol.3 (8), p.2351-2358 |
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Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Combining on-surface synthetic methods with the power of scanning tunneling microscopy to characterize novel materials at the single molecule level, we show how to steer the reactivity of one anthracene-based precursor towards different product nanostructures. Whereas using a Au(111) surface with three-fold symmetry results in the dominant formation of a starphene derivative, the two-fold symmetry of a reconstructed Au(110) surface allows the selective growth of non-benzenoid linear conjugated polymers. We further assess the electronic properties of each of the observed product structures
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tunneling spectroscopy and DFT calculations, altogether advancing the synthesis and characterization of molecular structures of notable scientific interest that have been only scarcely investigated to date, as applies both to starphenes and to non-benzenoid conjugated polymers.
We reveal the templating effect of substrates with two-fold or three-fold symmetry on the reactivity of acene-based reactants. This allows us to choose whether to form and characterize non-benzenoid conjugated polymers or starphene-derivatives. |
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ISSN: | 2516-0230 2516-0230 |
DOI: | 10.1039/d1na00126d |