Kinetically Controlled Fabrication of Single‐Crystalline TiO2 Nanobrush Architectures with High Energy {001} Facets

This study demonstrates that precise control of nonequilibrium growth conditions during pulsed laser deposition (PLD) can be exploited to produce single‐crystalline anatase TiO2 nanobrush architectures with large surface areas terminated with high energy {001} facets. The data indicate that the key...

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Bibliographic Details
Published in:Advanced science 2017-08, Vol.4 (8), p.n/a
Main Authors: Fan, Lisha, Gao, Xiang, Lee, Dongkyu, Guo, Er‐Jia, Lee, Shinbuhm, Snijders, Paul C., Ward, Thomas Z., Eres, Gyula, Chisholm, Matthew F., Lee, Ho Nyung
Format: Article
Language:English
Subjects:
defect‐mediated aggregation
high energy {001} facets
kinetic growth control
pulsed laser deposition
TiO2 nanostructures
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Summary:This study demonstrates that precise control of nonequilibrium growth conditions during pulsed laser deposition (PLD) can be exploited to produce single‐crystalline anatase TiO2 nanobrush architectures with large surface areas terminated with high energy {001} facets. The data indicate that the key to nanobrush formation is controlling the atomic surface transport processes to balance defect aggregation and surface‐smoothing processes. High‐resolution scanning transmission electron microscopy data reveal that defect‐mediated aggregation is the key to TiO2 nanobrush formation. The large concentration of defects present at the intersection of domain boundaries promotes aggregation of PLD growth species, resulting in the growth of the single‐crystalline nanobrush architecture. This study proposes a model for the relationship between defect creation and growth mode in nonequilibrium environments, which enables application of this growth method to novel nanostructure design in a broad range of materials. Vertically aligned single‐crystalline TiO2 nanobrushes with a large fraction of high energy {001} facets are fabricated with a precise kinetic growth control to balance the competition between defect‐mediated aggregation and surface smoothing processes using pulsed laser deposition.
ISSN:2198-3844
2198-3844
DOI:10.1002/advs.201700045