Crystal structure of (tert-butyl-dimethyl-sil-yl)tri-phenyl-germane, Ph3Ge-SiMe2(t-Bu)

In the title compound, Ph3Ge-SiMe2(t-Bu) or C24H30GeSi, the Si and Ge atoms both possess a tetra-hedral coordination environment with C-E-C (E = Si, Ge) angles in the range 104.47 (5)-114.67 (5)°. The mol-ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crysta...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-12, Vol.71 (Pt 12), p.o1015-o1016
Main Authors: Zaitsev, Kirill V, Zaitseva, Galina S, Karlov, Sergey S, Korlyukov, Alexander A
Format: Article
Language:English
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Data Reports
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Summary:In the title compound, Ph3Ge-SiMe2(t-Bu) or C24H30GeSi, the Si and Ge atoms both possess a tetra-hedral coordination environment with C-E-C (E = Si, Ge) angles in the range 104.47 (5)-114.67 (5)°. The mol-ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring mol-ecules are combined to dimers by six T-shaped C-H⋯π inter-actions, forming sixfold phenyl embraces (6PE).
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989015022872