N-Cyano-7α-methoxy-carbonyl-6,14-endo-ethenotetra-hydro-northebaine

methyl 17-cyano-3,6-dimeth-oxy-4,5α-ep-oxy-6,14-endo-ethenomorphinan-7-carboxyl-ate), C(23)H(24)N(2)O(5), the dihydro-furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo-hexene ring adopts an envelope conformation. An intra-molecular...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-08, Vol.65 (Pt 9), p.o2205-o2206
Main Authors: Odabaşoğlu, Mustafa, Yavuz, Serkan, Pamir, Ozgür, Büyükgüngör, Orhan, Yıldırır, Yılmaz
Format: Article
Language:English
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Organic Papers
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Summary:methyl 17-cyano-3,6-dimeth-oxy-4,5α-ep-oxy-6,14-endo-ethenomorphinan-7-carboxyl-ate), C(23)H(24)N(2)O(5), the dihydro-furan ring adopts a twist conformation, while the piperidine ring is in a chair conformation. The benzene-fused cyclo-hexene ring adopts an envelope conformation. An intra-molecular C-H⋯O hydrogen bond is observed. Inter-molecular C-H⋯N and C-H⋯O hydrogen bonds form C(5) chains along the a and b axes, respectively, and together they form a three-dimensional network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809032450