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A strategy to design highly efficient porphyrin sensitizers for dye-sensitized solar cells

We designed highly efficient porphyrin sensitizers with two phenyl groups at meso-positions of the macrocycle bearing two ortho-substituted long alkoxyl chains for dye-sensitized solar cells; the ortho-substituted devices exhibit significantly enhanced photovoltaic performances with the best porphyr...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (31), p.8910-8912
Main Authors: Chang, Yu-Cheng, Wang, Chin-Li, Pan, Tsung-Yu, Hong, Shang-Hao, Lan, Chi-Ming, Kuo, Hshin-Hui, Lo, Chen-Fu, Hsu, Hung-Yu, Lin, Ching-Yao, Diau, Eric Wei-Guang
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Language:English
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Summary:We designed highly efficient porphyrin sensitizers with two phenyl groups at meso-positions of the macrocycle bearing two ortho-substituted long alkoxyl chains for dye-sensitized solar cells; the ortho-substituted devices exhibit significantly enhanced photovoltaic performances with the best porphyrin, LD14, showing J(SC) = 19.167 mA cm(-2), V(OC) = 0.736 V, FF = 0.711, and overall power conversion efficiency η = 10.17%.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc12764k