Exceptional versatility of solvated block copolymer/ionomer networks as electroactive polymers

Responsive materials possess properties that change abruptly when exposed to an external stimulus, and electroactive polymers constitute examples of robust, lightweight materials that change shape upon electrical actuation. We demonstrate that solvated block copolymer networks afford tremendous vers...

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Bibliographic Details
Published in:Soft matter 2011-01, Vol.7 (5), p.1651-1655
Main Authors: Vargantwar, Pruthesh H, Shankar, Ravi, Krishnan, Arjun S, Ghosh, Tushar K, Spontak, Richard J
Format: Article
Language:English
Subjects:
Actuation
Block copolymers
Elastomers
Electroactive polymers
Networks
Solvents
Strain
Versatility
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Summary:Responsive materials possess properties that change abruptly when exposed to an external stimulus, and electroactive polymers constitute examples of robust, lightweight materials that change shape upon electrical actuation. We demonstrate that solvated block copolymer networks afford tremendous versatility in designing electronic and ionic electroactive polymers. As dielectric elastomers, styrenic block copolymer systems attain extraordinary actuation strains approaching 300%, along with high electromechanical coupling efficiencies. Changing the solvent improves the blocking stress and yields remarkably high energy densities, while providing a unique opportunity for mechanical impedance matching and control of shape recovery kinetics, as well as mode of deformation. Dielectric elastomers composed of acrylic copolymers actuate beyond 100% in-plane strain without any prestrain, whereas block ionomer networks swollen with ionic solutions yield ionic polymer-metal composites, which actuate by bending. Selective solvation of block copolymer networks represents an effective and largely unexplored means by which to tune the function and properties of electroactive polymers through systematic manipulation of copolymer and solvent attributes.
ISSN:1744-683X
DOI:10.1039/C0SM01210F