Optically active rhodium and iridium C sub(60) complexes containing the enantiomeric ligand (+)DIOP: (I times super(2)-C sub(60))MH(CO)[(+)DIOP] (M=Rh, Ir)

The fullerene-metal complexes (I. super(2)-C sub(60))MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh sub(3) in corresponding (I. super(2)-C sub(60))MH(CO)(PPh sub(3)) sub(2) for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(...

Full description

Saved in:
Bibliographic Details
Published in:Mendeleev communications 2011-10, Vol.21 (5), p.256-258
Main Authors: Tsikalova, Marina V, Zheludkov, Sergei V, Vorontsov, Evgenii I, Bashilov, Vasily V, Babievskii, Kirill K, Sokolov, Viatcheslav I, Novikov, Yurii N
Format: Article
Language:English
Subjects:
Buckminsterfullerene
Chelating
Fullerenes
Iridium
Ligands
Optical activity
Rhodium
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The fullerene-metal complexes (I. super(2)-C sub(60))MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh sub(3) in corresponding (I. super(2)-C sub(60))MH(CO)(PPh sub(3)) sub(2) for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino) e thane] and their structures assigned.
ISSN:0959-9436
DOI:10.1016/j.mencom.2011.09.008