A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

The first phosphine-free Pd-catalysed double carbonylation of aryl iodides is reported as a general and practical method, giving excellent conversions and selectivities for a wide range of aryl iodides and amine nucleophiles under atmospheric CO pressure.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (11), p.1695-1697
Main Authors: de la Fuente, Verónica, Godard, Cyril, Zangrando, Ennio, Claver, Carmen, Castillón, Sergio
Format: Article
Language:English
Subjects:
Amines
Aromatic compounds
Carbon monoxide
Carbon Monoxide - chemistry
Carbonyls
Catalysis
Conversion
Iodides
Iodides - chemistry
Nucleophiles
Palladium
Palladium - chemistry
Urea - analogs & derivatives
Urea - chemistry
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Description
Summary:The first phosphine-free Pd-catalysed double carbonylation of aryl iodides is reported as a general and practical method, giving excellent conversions and selectivities for a wide range of aryl iodides and amine nucleophiles under atmospheric CO pressure.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc17124d