A Multiferroic Perdeutero Metal-Organic Framework

Vitamin “D”: The perdeutero metal–organic framework [(CD3)2ND2][Co(DCOO)3] (see structure) undergoes two phase transitions, including one above room temperature, which is unprecedented for metal formates. Magnetic and dielectric hysteresis loops make it an example of a multiferroic MOF without coupl...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2011-12, Vol.50 (50), p.11947-11951
Main Authors: Fu, Da-Wei, Zhang, Wen, Cai, Hong-Ling, Zhang, Yi, Ge, Jia-Zhen, Xiong, Ren-Gen, Huang, Songping D., Nakamura, Takayoshi
Format: Article
Language:English
Subjects:
Dielectrics
Hysteresis loops
Joining
magnetic properties
Metal formates
Metal-organic frameworks
Order disorder
organic-inorganic hybrid composites
phase transitions
Two phase
Vitamins
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Summary:Vitamin “D”: The perdeutero metal–organic framework [(CD3)2ND2][Co(DCOO)3] (see structure) undergoes two phase transitions, including one above room temperature, which is unprecedented for metal formates. Magnetic and dielectric hysteresis loops make it an example of a multiferroic MOF without coupling of magnetic and electric ordering.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201103265