Preconcentration and separation of copper, nickel and zinc in aqueous samples by flame atomic absorption spectrometry after column solid-phase extraction onto MWCNTs impregnated with D2EHPA-TOPO mixture

A solid phase extraction method has been developed for the determination of copper, nickel and zinc ions in natural water samples. This method is based on the adsorption of copper, nickel and zinc on multiwalled carbon nanotubes (MWCNTs) impregnated with di-(2-ethyl hexyl phosphoric acid) (D2EHPA) a...

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Bibliographic Details
Published in:Journal of hazardous materials 2011-01, Vol.185 (2), p.1131-1139
Main Authors: Vellaichamy, S., Palanivelu, K.
Format: Article
Language:English
Subjects:
Adsorption
Applied sciences
Atomic absorption analysis
Chemical engineering
Copper
Copper - isolation & purification
D2EHPA
Enrichment
Exact sciences and technology
Extraction
FAAS
General purification processes
Heavy metals
Multiwalled carbon nanotubes
Nanotubes, Carbon
Nickel
Nickel - isolation & purification
Phosphoric Acids - chemistry
Pollution
Solid phase extraction
Solid Phase Extraction - methods
Spectrophotometry, Atomic - methods
Waste water
Wastewaters
Water - chemistry
Water treatment and pollution
Zinc
Zinc - isolation & purification
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Summary:A solid phase extraction method has been developed for the determination of copper, nickel and zinc ions in natural water samples. This method is based on the adsorption of copper, nickel and zinc on multiwalled carbon nanotubes (MWCNTs) impregnated with di-(2-ethyl hexyl phosphoric acid) (D2EHPA) and tri-n-octyl phosphine oxide (TOPO). The influence of parameters such as pH of the aqueous solution, amount of adsorbent, flow rates of the sample and eluent, matrix effects and D2EHPA-TOPO concentration have been investigated. Desorption studies have been carried out with 2 mol L −1 HNO 3. The copper, nickel and zinc concentrations were determined by flame atomic absorption spectrometry. The results indicated that the maximum adsorption of copper, nickel and zinc is at pH 5.0 with 500 mg of MWCNTs. The detection limits by three sigma were 50 μg L −1 for copper, 40 μg L −1 for nickel and 60 μg L −1 zinc. The highest enrichment factors were found to be 25. The adsorption capacity of MWCNTs-D2EHPA-TOPO was found to be 4.90 mg g −1 for copper, 4.78 mg g −1 for nickel and 4.82 mg g −1 for zinc. The developed method was applied for the determination of copper, nickel and zinc in electroplating wastewater and real water sample with satisfactory results (R.S.D.’s
ISSN:0304-3894
1873-3336
DOI:10.1016/j.jhazmat.2010.10.023