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Pedogenic carbonate carbon isotopic constraints on paleoprecipitation: Evolution of desert in the Pacific Northwest, USA, in response to topographic development of the Cascade Range
The Cascade Range in the northwestern U.S. acts as an orographic barrier to the easterly movement of humid air masses from the Pacific Ocean, producing a massive rain shadow with arid to semi-arid climate conditions on the leeward side of the range. Pedogenic carbonates formed in the C 3-dominated l...
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Published in: | Chemical geology 2010-10, Vol.277 (3), p.323-335 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The Cascade Range in the northwestern U.S. acts as an orographic barrier to the easterly movement of humid air masses from the Pacific Ocean, producing a massive rain shadow with arid to semi-arid climate conditions on the leeward side of the range. Pedogenic carbonates formed in the C
3-dominated landscapes east of the range have δ
13C
carbonate that is enriched by approximately 4‰ relative to carbonates formed in sub-tropical C
3-dominated ecosystems. We measured stable isotopic compositions of pedogenic carbonates preserved in the Quaternary and Neogene sedimentary rock units in the inland Pacific Northwest, and examined the impact of long-term aridification and paleohydrology on their isotopic compositions. The determined δ
13C
carbonate record shows a gradual increase of 5‰ from approximately −
10‰ in older pedogenic carbonates to −
5‰ in younger ones whereas δ
18O
carbonate record indicates a decrease of approximately 4‰ in the late Neogene. In addition, the Quaternary δ
13C
carbonate and δ
18O
carbonate records indicate the highest δ
13C and δ
18O among the samples during the Pleistocene and significant fluctuation over the time period. The gradual increase in the δ
13C
carbonate and the decrease in the δ
18O
carbonate in the late Neogene are interpreted by the development of the rain shadow as a result of topographic development of the Cascade Range. Changes in the Quaternary isotope records suggest a decrease in regional precipitation and isotopically depleted winter precipitation, resulting from changes in large-scale atmospheric circulation patterns due to advance and retreat of northern hemisphere continental ice sheet. The isotope record from pedogenic carbonates provides a direct record of climatic change, suggesting that long-term carbon isotope data can provide useful constraints on timing and intensity of regional desertification, and its associated climate and topographic interaction.
► Deserts exist on the leeward side of mountain ranges. ► δ
13C of pedogenic carbonates increase with decreasing in MAP. ► Cenozoic ™13C
soil carbonate in the Pacific Northwest increases with decreasing age. ► Evolution of the Cascade Range resulted in the regional desertification. |
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ISSN: | 0009-2541 1872-6836 |
DOI: | 10.1016/j.chemgeo.2010.08.015 |