Designing new V–Sb–O based catalysts on mesoporous supports for nitriles production

Depending on the morphology and chemical composition of the support, method of active phase loading, and temperature of calcination, different Sb–V–O structures can be obtained, which modulates the activity, being possible the design of selective catalysts towards acrylonitrile or to acetonitrile. T...

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Bibliographic Details
Published in:Applied catalysis. A, General General, 2010-05, Vol.380 (1), p.95-104
Main Authors: Golinska, H., Rojas, E., López-Medina, R., Calvino-Casilda, V., Ziolek, M., Bañares, M.A., Guerrero-Pérez, M.O.
Format: Article
Language:English
Subjects:
Acetonitrile
Acrylonitrile
Acrylonitriles
Ammoxidation
Antimony
Catalysis
Catalysts
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Materials selection
Mesoporous materials
Niobium
Porous materials
Propane
Selectivity
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
V-Sb-O catalysts
Vanadium
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Summary:Depending on the morphology and chemical composition of the support, method of active phase loading, and temperature of calcination, different Sb–V–O structures can be obtained, which modulates the activity, being possible the design of selective catalysts towards acrylonitrile or to acetonitrile. The effect of Sb/V molar ratio, textural morphology and chemical composition of the support on the catalytic behavior has been studied during acrylonitrile formation from both propane and glycerol, in the gas and in the liquid phase, respectively. Results nicely show that depending on the presence or absence of sodium cations, the method of Sb–V–O loading, and the calcination temperature, different Sb–V–O structures can be obtained at the catalyst surface. The nature of heteroatom included into mesoporous structure (Al or Nb) does not influence the type of crystal phases formed. Vanadium species remain in different oxidation states in such structures, which drastically affect the catalytic behavior so that it is possible to design catalysts towards high selectivity to acrylonitrile or to acetonitrile. In addition, the role of the niobium as dopant of these catalytic materials has been studied, and it is shown that in mesoporous materials, niobium is able to increase both activity and selectivity to N insertion.
ISSN:0926-860X
1873-3875
DOI:10.1016/j.apcata.2010.03.037