Straightforward Generation of Helical Chirality Driven by a Versatile Heteroscorpionate Ligand: Self-Assembly of a Metal Helicate by Using CHπ Interactions

In a twist: The synthesis of novel architectures, through the use of versatile heteroscorpionate ligands, was developed that allows helical chirality in aluminium complexes (see figure).

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Bibliographic Details
Published in:Chemistry : a European journal 2010-08, Vol.16 (29), p.8615-8619
Main Authors: Otero, Antonio, Lara-Sánchez, Agustín, Fernández-Baeza, Juan, Alonso-Moreno, Carlos, Tejeda, Juan, Castro-Osma, José A., Márquez-Segovia, Isabel, Sánchez-Barba, Luis F., Rodríguez, Ana M., Gómez, M. Victoria
Format: Article
Language:English
Subjects:
Aluminium
Aluminum
Architecture
Chirality
CHpi interactions
Helical
heteroscorpionate ligands
Ligands
Self assembly
Synthesis
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Description
Summary:In a twist: The synthesis of novel architectures, through the use of versatile heteroscorpionate ligands, was developed that allows helical chirality in aluminium complexes (see figure).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201000694