Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation

Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various fu...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-05, Vol.49 (21), p.3627-3630
Main Authors: Yu, Liting, Wang, Zheng, Wu, Jiang, Tu, Shujiang, Ding, Kuiling
Format: Article
Language:English
Subjects:
asymmetric catalysis
Catalysis
heterogeneous catalysis
Hydrogenation
Microscopy, Electron, Scanning
Molecular Structure
Polymers - chemistry
rhodium
Rhodium - chemistry
Stereoisomerism
supramolecular chemistry
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Summary:Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various functionalized olefin derivatives.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200906405