Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V(2)O(2)F(5)] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This su...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (26), p.6018-6020
Main Authors: Himeur, Farida, Allan, Phoebe K, Teat, Simon J, Goff, Richard J, Morris, Russell E, Lightfoot, Philip
Format: Article
Language:English
Subjects:
Condensing
Media
Networks
Oxyfluorides
Prints
Routing (telecommunications)
Synthesis
Vanadium
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Summary:A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V(2)O(2)F(5)] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.
ISSN:1477-9226
1477-9234
DOI:10.1039/c000318b