Acid digestion of geological and environmental samples using open-vessel focused microwave digestion

The application of open vessel focused microwave acid digestion is described for the preparation of geological and environmental samples for analysis using inductively coupled plasma-mass spectrometry (ICP-MS). The method is compared to conventional closed-vessel high pressure methods which are limi...

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Bibliographic Details
Published in:Analytical and bioanalytical chemistry 2002-01, Vol.372 (2), p.360-365
Main Authors: Taylor, Vivien F, Toms, Andrew, Longerich, Henry P
Format: Article
Language:English
Subjects:
Acids, Noncarboxylic - chemistry
Equipment Design
Geologic Sediments - analysis
Hot Temperature
Metals, Heavy - analysis
Microwaves
Plants - chemistry
Reference Standards
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Summary:The application of open vessel focused microwave acid digestion is described for the preparation of geological and environmental samples for analysis using inductively coupled plasma-mass spectrometry (ICP-MS). The method is compared to conventional closed-vessel high pressure methods which are limited in the use of HF to break down silicates. Open-vessel acid digestion more conveniently enables the use of HF to remove Si from geological and plant samples as volatile SiF4, as well as evaporation-to-dryness and sequential acid addition during the procedure. Rock reference materials (G-2 granite, MRG-1 gabbros, SY-2 syenite, JA-1 andesite, and JB-2 and SRM-688 basalts) and plant reference materials (BCR and IAEA lichens, peach leaves, apple leaves, Durham wheat flour, and pine needles) were digested with results comparable to conventional hotplate digestion. The microwave digestion method gave poor results for granitic samples containing refractory minerals, however fusion was the preferred method of preparation for these samples. Sample preparation time was reduced from several days, using conventional hotplate digestion method, to one hour per sample using our microwave method.
ISSN:1618-2642
1618-2650
DOI:10.1007/s00216-001-1172-z