Palladium-Catalyzed Bisdiene Carbocyclizations:  A Facile [3 + 2] Cycloaddition Reaction Mode

In contrast to alkyl-substituted bisdienes, aryl-substituted substrates undergo surprisingly facile palladium-catalyzed carbocyclization via a novel [3 + 2] cycloaddition mode.

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Bibliographic Details
Published in:Organic letters 2003-11, Vol.5 (23), p.4317-4320
Main Authors: Takacs, James M, Leonov, Alexei P
Format: Article
Language:English
Subjects:
Catalysis
Palladium - chemistry
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Description
Summary:In contrast to alkyl-substituted bisdienes, aryl-substituted substrates undergo surprisingly facile palladium-catalyzed carbocyclization via a novel [3 + 2] cycloaddition mode.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol035569u