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Catalytic Asymmetric Esterification of Ketenes
Ketene esterification after 100 years: In the latest advance in the esterification of ketenes, Schaefer and Fu described the catalytic asymmetric conversion of 2‐tolyl(ethyl)ketene (1) and diphenylacetaldehyde to give the enol ester 2 in 99 % yield and 98 % ee (see scheme).
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Published in: | Angewandte Chemie (International ed.) 2005-10, Vol.44 (42), p.6812-6814 |
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container_end_page | 6814 |
container_issue | 42 |
container_start_page | 6812 |
container_title | Angewandte Chemie (International ed.) |
container_volume | 44 |
creator | Tidwell, Thomas T. |
description | Ketene esterification after 100 years: In the latest advance in the esterification of ketenes, Schaefer and Fu described the catalytic asymmetric conversion of 2‐tolyl(ethyl)ketene (1) and diphenylacetaldehyde to give the enol ester 2 in 99 % yield and 98 % ee (see scheme). |
doi_str_mv | 10.1002/anie.200501849 |
format | article |
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chemical synthesis</topic><topic>Ethylenes - chemistry</topic><topic>homogeneous catalysis</topic><topic>ketenes</topic><topic>Ketones - chemical synthesis</topic><topic>Ketones - chemistry</topic><topic>Molecular Structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tidwell, Thomas T.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tidwell, Thomas T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Asymmetric Esterification of Ketenes</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angewandte Chemie International Edition</addtitle><date>2005-10-28</date><risdate>2005</risdate><volume>44</volume><issue>42</issue><spage>6812</spage><epage>6814</epage><pages>6812-6814</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><notes>ArticleID:ANIE200501849</notes><notes>Financial support by the Natural Sciences and Engineering Research Council of Canada is gratefully acknowledged</notes><notes>istex:BAF90188918223514160846BF9289B7E1514E8F8</notes><notes>ark:/67375/WNG-HJSVNL06-T</notes><notes>ObjectType-Article-2</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-3</notes><notes>content type line 23</notes><notes>ObjectType-Review-1</notes><abstract>Ketene esterification after 100 years: In the latest advance in the esterification of ketenes, Schaefer and Fu described the catalytic asymmetric conversion of 2‐tolyl(ethyl)ketene (1) and diphenylacetaldehyde to give the enol ester 2 in 99 % yield and 98 % ee (see scheme).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>16161176</pmid><doi>10.1002/anie.200501849</doi><tpages>3</tpages></addata></record> |
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source | Wiley-Blackwell Journals |
subjects | asymmetric catalysis Catalysis enol esters Esterification Ethylenes - chemical synthesis Ethylenes - chemistry homogeneous catalysis ketenes Ketones - chemical synthesis Ketones - chemistry Molecular Structure |
title | Catalytic Asymmetric Esterification of Ketenes |
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