Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality

An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].

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Bibliographic Details
Published in:Organic letters 2007-01, Vol.9 (2), p.223-226
Main Authors: Axe, Philip, Bull, Steven D, Davidson, Matthew G, Gilfillan, Carly J, Jones, Matthew D, Robinson, Diane E J E, Turner, Luke E, Mitchell, William L
Format: Article
Language:English
Subjects:
Crystallography, X-Ray
Ligands
Magnetic Resonance Spectroscopy - methods
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
Sensitivity and Specificity
Stereoisomerism
Titanium - chemistry
Online Access:Get full text
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Description
Summary:An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].
ISSN:1523-7060
1523-7052
DOI:10.1021/ol062655w