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Secondary and primary relaxations in hyperbranched polyglycerol:A comparative study in the frequency and time domains
The non-Debye relaxation behavior of hyperbranched polyglycerol was investigated by broadband dielectric spectroscopy. A thorough study of the relaxations was carried out paying special attention to truncation effects on deconvolutions of overlapping processes. Hyperbranched polyglycerol exhibits tw...
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| Published in: | The Journal of chemical physics 2007-09, Vol.127 (12), p.124904-124904-10 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
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| Summary: | The non-Debye relaxation behavior of hyperbranched polyglycerol was investigated by broadband dielectric spectroscopy. A thorough study of the relaxations was carried out paying special attention to truncation effects on deconvolutions of overlapping processes. Hyperbranched polyglycerol exhibits two relaxations in the glassy state named in increasing order of frequency
β
and
γ
processes. The study of the evolution of these two fast processes with temperature in the time retardation spectra shows that the
β
absorption is swallowed by the
α
in the glass-liquid transition, the
γ
absorption being the only relaxation that remains operative in the liquid state. In heating, a temperature is reached at which the
α
absorption vanishes appearing the
α
γ
relaxation. Two characteristics of
α
absorptions, decrease of the dielectric strength with increasing temperature and rather high activation energy, are displayed by the
α
γ
process. Williams' ansatz seems to hold for these topologically complex macromolecules. |
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| ISSN: | 0021-9606 1089-7690 |
| DOI: | 10.1063/1.2780153 |