Poly[[μ-aqua-bis­(μ-2,4-dichloro­phen­oxy­acetato)barium(II)] monohydrate]

In the title coordination polymer, {[Ba(C8H5Cl2O3)2(H2O)]·H2O}n, each BaII atom is nine‐coordinated by six carboxyl­ate O atoms and one ether O atom from five symmetry‐related 2,4‐dichloro­phenoxy­acetate ligands, and by two O atoms from water mol­ecules, thus defining a distorted tricapped trigonal...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-11, Vol.62 (11), p.m516-m518
Main Authors: Gu, Chang-Sheng, Hao, Xiao-Min, Guan, Shu-Xia, Liu, Ji-Wei
Format: Article
Language:English
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Summary:In the title coordination polymer, {[Ba(C8H5Cl2O3)2(H2O)]·H2O}n, each BaII atom is nine‐coordinated by six carboxyl­ate O atoms and one ether O atom from five symmetry‐related 2,4‐dichloro­phenoxy­acetate ligands, and by two O atoms from water mol­ecules, thus defining a distorted tricapped trigonal prism. The BaII ions are bridged by bidentate water mol­ecules and by tridentate and tetra­dentate 2,4‐dichloro­phenoxy­acetate groups, leading to a two‐dimensional layer structure. The crystal structure is further stabilized by hydrogen‐bonding inter­actions within each layer.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270106037565