The [NH3Cl]+ Ion

Stable! The first stable salts containing a simple, inorganic cation with an NCl bond are prepared (see picture). They are [NH3Cl]+[BF4]−, [NH3Cl]+[AsF6]−, and [NH3Cl]+[SbF6]− and can be safely prepared from (Me3Si)2NCl in mixtures of HF and the corresponding Lewis acids and could be used as storab...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2004-10, Vol.43 (39), p.5213-5217
Main Authors: Schneider, Stefan, Haiges, Ralf, Schroer, Thorsten, Boatz, Jerry, Christe, Karl O.
Format: Article
Language:English
Subjects:
cations
nitrogen chlorides
NMR spectroscopy
theoretical chemistry
vibrational spectroscopy
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Summary:Stable! The first stable salts containing a simple, inorganic cation with an NCl bond are prepared (see picture). They are [NH3Cl]+[BF4]−, [NH3Cl]+[AsF6]−, and [NH3Cl]+[SbF6]− and can be safely prepared from (Me3Si)2NCl in mixtures of HF and the corresponding Lewis acids and could be used as storable generators for monochloramine gas.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460544