Polyazido High-Nitrogen Compounds: Hydrazo- and Azo-1,3,5-triazine

20 nitrogens and six carbons: The compounds 1 and 2, demonstrate that hydrazo and azo linkages can be used to desensitize polyazido high‐nitrogen compounds and also decrease their volatility. The compound 2 has the highest experimentally measured heat of formation reported for energetic organic comp...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2004-09, Vol.43 (37), p.4924-4928
Main Authors: Huynh, My-Hang V., Hiskey, Michael A., Hartline, Ernest L., Montoya, Dennis P., Gilardi, Richard
Format: Article
Language:English
Subjects:
azides
explosives
heat of formation
high energy-density materials (HEDM)
nitrogen
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Summary:20 nitrogens and six carbons: The compounds 1 and 2, demonstrate that hydrazo and azo linkages can be used to desensitize polyazido high‐nitrogen compounds and also decrease their volatility. The compound 2 has the highest experimentally measured heat of formation reported for energetic organic compounds (+2171 kJ mol−1).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460366