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Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)

Reaction of [Cu(MeCN)4]+ with thiosemicarbazones bearing groups such as phenol, pyridine, or ferrocene gives tetranuclear or hexanuclear clusters with functional substituents; analogous air stable fluorescent clusters can also be prepared with Ag(I).

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Bibliographic Details
Published in:Inorganic chemistry 2004-07, Vol.43 (14), p.4121-4123
Main Authors: Ashfield, Laura J, Cowley, Andrew R, Dilworth, Jonathan R, Donnelly, Paul S
Format: Article
Language:English
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Description
Summary:Reaction of [Cu(MeCN)4]+ with thiosemicarbazones bearing groups such as phenol, pyridine, or ferrocene gives tetranuclear or hexanuclear clusters with functional substituents; analogous air stable fluorescent clusters can also be prepared with Ag(I).
ISSN:0020-1669
1520-510X
DOI:10.1021/ic035451+