High Molecular Weight Poly(butyl methacrylate) via ATRP Miniemulsions

The reverse atom transfer radical polymerization of butyl methacrylate in miniemulsion, initiated with the redox pair hydrogen peroxide/ascorbic acid and mediated with copper(II) bromide tris[2-di(2-ethylhexyl acrylate)aminoethyl]amine is capable of producing well-controlled high-molecular weight po...

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Bibliographic Details
Published in:Macromolecular symposia 2008, Vol.261 (1), p.32-35
Main Authors: Simms, Ryan W, Cunningham, Michael F
Format: Article
Language:English
Subjects:
Applied sciences
Ascorbic acid
atom transfer radical polymerization (ATRP)
Atomic properties
Bromides
Exact sciences and technology
high molecular weight
Hydrogen peroxide
miniemulsion
Molecular weight
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
Radicals
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Summary:The reverse atom transfer radical polymerization of butyl methacrylate in miniemulsion, initiated with the redox pair hydrogen peroxide/ascorbic acid and mediated with copper(II) bromide tris[2-di(2-ethylhexyl acrylate)aminoethyl]amine is capable of producing well-controlled high-molecular weight poly(butyl methacrylate).
ISSN:1022-1360
1521-3900
DOI:10.1002/masy.200850105