Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives

Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives

A PPh3Au­[B­(C6F5)4]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o-Quinodimethane (o-QDM) intermediate’s extended conjugated addition process. The reaction has the advantages of wide substrate scopes...

Full description

Saved in:
Bibliographic Details
Published in:Journal of organic chemistry 2024-05, Vol.89 (9), p.6074-6084
Main Authors: Hao, Jun-Jie, Wu, Juan, Jiang, Tao, Luo, Hejiang, Li, Rong-Tao
Format: Article
Language:eng
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A PPh3Au­[B­(C6F5)4]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o-Quinodimethane (o-QDM) intermediate’s extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
ISSN:0022-3263
1520-6904