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Low-temperature crystallization of sol–gel-derived lead zirconate titanate thin films using 2.45 GHz microwaves

Lead zirconate titanate (PZT) thin films of thickness 420 nm were deposited on Pt/Ti/SiO 2/Si substrate using a spin coating sol–gel precursor solution, and then annealed using 2.45 GHz microwaves at a temperature of 450 °C for 30 min. The film has a high perovskite content and high crystallinity wi...

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Bibliographic Details
Published in:Thin solid films 2007-01, Vol.515 (5), p.2891-2896
Main Authors: Bhaskar, Ankam, Chang, T.H., Chang, H.Y., Cheng, S.Y.
Format: Article
Language:English
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Summary:Lead zirconate titanate (PZT) thin films of thickness 420 nm were deposited on Pt/Ti/SiO 2/Si substrate using a spin coating sol–gel precursor solution, and then annealed using 2.45 GHz microwaves at a temperature of 450 °C for 30 min. The film has a high perovskite content and high crystallinity with a full width at half maximum of 0.35°. The surface roughness of the PZT thin film was 1.63 nm. Well-saturated ferroelectric properties were obtained with a remanent polarization of 46.86 μC/cm 2 and coercive field of 86.25 kV/cm. The film also exhibited excellent dielectric properties with a dielectric constant of 1140 and a dissipation factor of 0.03. These properties are superior to those obtained by conventional annealing at a temperature of 700 °C for 30 min.
ISSN:0040-6090
1879-2731
DOI:10.1016/j.tsf.2006.08.044