A Two-Dimensional Porphyrin-Based Porous Network Featuring Communicating Cavities for the Templated Complexation of Fullerenes

An unprecedented two‐dimensional porphyrin network featuring dynamic pores capable of hosting fullerenes is realized following a bottom‐up approach at a single‐crystal silver surface. Surface‐ and porphyrin‐driven long‐range interactions between the C60 guest molecules and porphyrin layer result in...

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2006-02, Vol.18 (3), p.275-279
Main Authors: Spillmann, H., Kiebele, A., Stöhr, M., Jung, T. A., Bonifazi, D., Cheng, F., Diederich, F.
Format: Article
Language:English
Subjects:
Fullerenes
Host-guest systems
Porphyrins
Self-assembly
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Summary:An unprecedented two‐dimensional porphyrin network featuring dynamic pores capable of hosting fullerenes is realized following a bottom‐up approach at a single‐crystal silver surface. Surface‐ and porphyrin‐driven long‐range interactions between the C60 guest molecules and porphyrin layer result in the formation of exceptionally large supramolecular hybrid chains and islands (see Figure and Cover).
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200501734