Predicting natural arsenic enrichment in peat-bearing, alluvial and coastal depositional systems: A generalized model based on sequence stratigraphy

Hazardously high concentrations of arsenic exceeding the threshold limits for soils and drinking waters have been widely reported from Quaternary sedimentary successions and shallow aquifers of alluvial and coastal lowlands worldwide, raising public health concerns due to potential human exposure to...

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Bibliographic Details
Published in:The Science of the total environment 2024-05, Vol.924, p.171571-171571, Article 171571
Main Authors: Amorosi, Alessandro, Sammartino, Irene
Format: Article
Language:English
Subjects:
Aquifer
Contamination
Delta
Geochemistry
Po Plain
Quaternary
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Summary:Hazardously high concentrations of arsenic exceeding the threshold limits for soils and drinking waters have been widely reported from Quaternary sedimentary successions and shallow aquifers of alluvial and coastal lowlands worldwide, raising public health concerns due to potential human exposure to arsenic. A combined sedimentological and geochemical analysis of subsurface deposits, 2.5–50 m deep, from the SE Po Plain (Italy) documents a systematic tendency for naturally-occurring arsenic to accumulate in peat-rich layers, with concentrations invariably greater than maximum permissible levels. A total of 366 bulk sediment samples from 40 cores that penetrated peat-bearing deposits were analysed by X-ray fluorescence. Arsenic concentrations associated with 7 peat-free lithofacies associations (fluvial-channel, levee/crevasse, floodplain, swamp, lagoon/bay, beach-barrier, and offshore/prodelta) exhibit background values invariably below threshold levels (
ISSN:0048-9697
1879-1026
DOI:10.1016/j.scitotenv.2024.171571