Effect of competitive interactions on the structure and properties of blends prepared from an industrial lignosulfonate polymer

To explore the possibility of applying lignin in practice, an industrial lignosulfonate (0-50 vol%) was blended with four ionomers. The concentrations of carboxyl and carboxylate groups were systematically varied in the ethylene-acrylic acid copolymers to study the competition of hydrogen and ionic...

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Bibliographic Details
Published in:International journal of biological macromolecules 2024-01, Vol.254 (Pt 2), p.127694-127694, Article 127694
Main Authors: Pregi, Emese, Blasius, Jan, Kun, Dávid, Hollóczki, Oldamur, Pukánszky, Béla
Format: Article
Language:English
Subjects:
Lignin - chemistry
Polymers - chemistry
Tensile Strength
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Summary:To explore the possibility of applying lignin in practice, an industrial lignosulfonate (0-50 vol%) was blended with four ionomers. The concentrations of carboxyl and carboxylate groups were systematically varied in the ethylene-acrylic acid copolymers to study the competition of hydrogen and ionic bonds forming between the components. The mechanical properties of the blends were determined by tensile testing. The structure was investigated by scanning electron microscopy, while deformation and failure processes were studied by acoustic emission measurements and microscopy. Interfacial interactions were quantitatively characterized by analyzing local deformation processes and by evaluating the composition dependence of the tensile strength using appropriate models. Molecular dynamics simulations indicated that carboxylate groups preferably form clusters in the ionomer phase, consequently, the increasing degree of neutralization results in ionomers with more and more self-interactions of components deteriorating ionomer-lignin interactions. The novel combination of experiments, modeling, and simulation was done for the first time on such materials, and it pointed out that the role of hydrogen bonds is more critical in determining blend properties. Blends can be prepared for practical applications with a good combination of stiffness (0.8 GPa), tensile strength (22 MPa), and elongation-at-break (25 %) at 30 vol% lignosulfonate content and 33 % neutralization.
ISSN:0141-8130
1879-0003
DOI:10.1016/j.ijbiomac.2023.127694